110-57-6
- Product Name：trans-1,4-Dichloro-2-butene
- Molecular Formula：C4H6Cl2
- Purity：97% GC
- Molecular Weight：124.998
Product Details
Perfect Factory Offer Excellent quality trans-1,4-Dichloro-2-butene 110-57-6 with Safe Shipping
- Molecular Formula:C4H6Cl2
- Molecular Weight:124.998
- Appearance/Colour:clear colorless to light yellow liquid
- Vapor Pressure:10 mm Hg ( 20 °C)
- Melting Point:1-3 °C
- Refractive Index:n20/D 1.488(lit.)
- Boiling Point:125.5 °C at 760 mmHg
- Flash Point:33.3 °C
- PSA：0.00000
- Density:1.13 g/cm3
- LogP:2.02020
trans-1,4-Dichloro-2-butene(Cas 110-57-6) Usage
|
Synthesis Reference(s) |
Journal of the American Chemical Society, 73, p. 2118, 1951 DOI: 10.1021/ja01149a061The Journal of Organic Chemistry, 36, p. 2088, 1971 DOI: 10.1021/jo00814a013 |
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Air & Water Reactions |
Insoluble in water. |
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Reactivity Profile |
trans-1,4-Dichloro-2-butene will burn, though trans-1,4-Dichloro-2-butene may require some effort to ignite. Fire produces irritating and poisonous gases. When heated to decomposition, trans-1,4-Dichloro-2-butene emits toxic fumes of chlorine-containing compounds. [EPA, 1998]. |
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Health Hazard |
(Non-Specific -- Dichlorobutene) Liquid and vapors from the material are highly corrosive and may damage skin, eyes, lungs, and internal organs. |
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Fire Hazard |
The material will burn, though trans-1,4-Dichloro-2-butene may require some effort to ignite. Fire produces irritating and poisonous gases. When heated to decomposition, trans-1,4-Dichloro-2-butene emits toxic fumes of chlorine-containing compounds. |
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Potential Exposure |
DC occurs as a by-product in chloroprene manufacture and may be used as a chemical intermediate |
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Shipping |
UN3384 Toxic by inhalation liquid, flammable, n. o.s. with an LC50 ≦ 1000 ml/m3 and saturated vapor concentration ≧to 10 LC50, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid, Technical Name Required, Inhalation Hazard Zone B. UN2920 Corrosive liquids, flammable, n.o.s., Hazard class: 8; Labels: 8-Corrosive material, 3-Flammable liquid. The code “D” identifies proper shipping names which are appropriate for describing materials for domestic transportation but may be inappropriate for international transportation under the provisions of international regulations, e.g., IMO, ICAO). An alternate proper shipping name may be selected when either domestic or international transportation is involved |
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Incompatibilities |
Vapors may form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. (cis-isomer): Reacts slowly with water forming hydrogen chloride. Attacks metals and may form other, more dangerous materials; attacks some plastics. |
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Waste Disposal |
High-temperature incineration with hydrochloric acid scrubbing. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. |
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General Description |
Colorless liquid with a distinct odor. An intermediate for hexamethylenediamine and chloroprene. |
InChI:InChI=1/C4H6Cl2/c5-3-1-2-4-6/h1,3H,2,4H2
110-57-6 Relevant articles
[2+2] Photocycloaddition of symmetrically disubstituted alkenes to 2(5H)-furanones: Diastereoselective entry to 1,2,3,4-tetrasubstituted cyclobutanes
Pares, Sonia,De March, Pedro,Font, Josep,Alibes, Ramon,Figueredo, Marta
, p. 3888 - 3895 (2011)
A study on the [2+2] photochemical cyclo...
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Baird,W.C. et al.
, p. 3324 - 3330 (1971)
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Catalytic conversions of chloroolefins over iron oxide nanoparticles: 1. Isomerization of dichlorobutenes in the presence of iron oxide nanopaticles immobilized on silicas with different structures
Rostovshchikova,Smirnov,Tsodikov,Bukhtenko,Maksimov,Kiseleva,Pankratov
, p. 1418 - 1424 (2005)
The influence of the support nature and ...
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Mislow,Hellman
, p. 244,246 (1951)
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Catalytic conversions of chloroolefins over iron oxide nanoparticles 2. Isomerization of dichlorobutenes over iron oxide nanoparticles stabilized on the surface of ultradispersed poly(tetrafluoroethylene)
Rostovshchikova,Korobov,Pankratov,Yurkov,Gubin
, p. 1425 - 1432 (2005)
Nanosized iron oxides stabilized on the ...
Kinetics of inversion of dichlorobutene in the heterogeneous system
Langeroodi, N. Samadani
experimental part, p. 2772 - 2774 (2012/08/28)
The reaction kinetics of the isomerizati...
Isomerization of 3,4-dichloro-1-butene into 1,4-dichloro-2-butene by heterogeneous catalysis
Langeroodi, Narges Samadani
experimental part, p. 125 - 128 (2011/10/05)
The isomerization of 3,4-dichloro-1-bute...
Catalytic conversions of chloroolefines over iron oxide nanoparticles 3. Electronic and magnetic properties of γ-Fe2O3 nanoparticles immobilized on different silicas
Rostovshchikova,Kiseleva,Smirnov,Maksimov,Suzdalev,Prusakov,Tsodikov,Ikorskii
, p. 1768 - 1774 (2008/02/05)
Catalytic properties of superparamagneti...
110-57-6 Process route
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106-99-0,130983-70-9,29406-96-0,9003-17-2
buta-1,3-diene
-
-
110-57-6
trans-1,4-dichlorobut-2-ene
-
-
310447-99-5,310448-01-2,64037-54-3
3,4-dichlorobut-1-ene
| Conditions | Yield |
|---|---|
|
With
chlorine;
at 60 - 75 ℃;
in der Dampfphase;
|
|
|
With
chlorine;
at 60 - 75 ℃;
in verschiedenen Loesungsmitteln unter Kuehlung;
|
|
|
at 25 ℃;
electrolysis; anolyte=CoCl2-MeCN, catholyte=NH4Cl-H2O;
|
|
|
With
chlorine;
In
dichloromethane;
further solvent: CCl4;
|
|
|
With
chlorine;
at 60 - 75 ℃;
in der Dampfphase;
|
|
|
With
chlorine;
at 60 - 75 ℃;
in verschiedenen Loesungsmitteln unter Kuehlung;
|
-
-
106-99-0,130983-70-9,29406-96-0,9003-17-2
buta-1,3-diene
-
-
110-57-6
trans-1,4-dichlorobut-2-ene
| Conditions | Yield |
|---|---|
|
With
tetrachloromethane; chlorine;
at -80 ℃;
unter Lichtausschluss;
|
|
|
With
pyridine; tetrachloromethane; chlorine;
at -80 ℃;
unter Lichtausschluss;
|
110-57-6 Upstream products
-
310447-99-5
3,4-dichlorobut-1-ene
-
106-99-0
buta-1,3-diene
-
764-41-0
1,4-dichloro-2-butene
-
67-56-1
methanol
110-57-6 Downstream products
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22805-71-6
(E)-1,4-dimethoxy-2-butene
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627-22-5
1-chloroprene
-
26649-88-7
(E/Z)-1,4-dipropoxybut-2-ene
-
40930-37-8
1,4-diamino-trans-2-butene
Relevant Products
-
(R)-(+)-2-Chloropropionic acidCAS：7474-05-7
-
cis-1,4-Dichloro-2-buteneCAS：1476-11-5
-
Ethyl vinyl sulfoneCAS：1889-59-4