29263-94-3
- Product Name：Diethyl 2-bromo-2-methylmalonate
- Molecular Formula：C8H13BrO4
- Purity：99% GC
- Molecular Weight：253.093
Product Details
Factory Export Top Purity Diethyl 2-bromo-2-methylmalonate 29263-94-3 In Stock
- Molecular Formula:C8H13BrO4
- Molecular Weight:253.093
- Appearance/Colour:clear, colorless liquid
- Vapor Pressure:0.0433mmHg at 25°C
- Refractive Index:n20/D 1.449(lit.)
- Boiling Point:238.04 °C at 760 mmHg
- Flash Point:97.764 °C
- PSA：52.60000
- Density:1.4 g/cm3
- LogP:1.26620
Diethyl 2-bromo-2-methylmalonate(Cas 29263-94-3) Usage
|
General Description |
Diethyl 2-bromo-2-methylmalonate acts as initiator during the atom transfer radical polymerization of methyl methacrylate. |
InChI:InChI=1/C8H13BrO4/c1-4-12-6(10)8(3,9)7(11)13-5-2/h4-5H2,1-3H3
29263-94-3 Relevant articles
N,N-Dibromobenzenesulfonamide: A useful regenrable reagent for bromination of various carbanionic substrates
Tajbakhsh, Mahmood,Khazaei, Ardeshir,Mahalli, Majid Shabani,Vaghi, Ramin Ghorbani
, p. 1159 - 1163 (2007/10/03)
N,N-Dibromobenzenesulfonamide(dibromoami...
One-pot synthesis using supported reagents system: Conversion of β-dicarbonyl compounds to α-thiocyano-β-dicarbonyl compounds using CuBr2/Al2O3-KSCN/SiO2
Suzuki, Yoshitada,Kodomari, Mitsuo
, p. 1091 - 1092 (2007/10/03)
Transformation of β-dicarbonyl compound ...
Rate Constants for Halogen Atom Transfer from Representative α-Halocarbonyl Compounds to Primary Alkyl Radicals
Curran, Dennis P.,Bosch, Eric,Kaplan, Jere,Newcomb, Martin
, p. 1826 - 1831 (2007/10/02)
Rate constants for halogen atom transfer...
29263-94-3 Process route
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609-08-5
Diethyl methylmalonate
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29263-94-3
diethyl bromomethylmalonate
| Conditions | Yield |
|---|---|
|
With
aluminum oxide; copper(ll) bromide;
In
acetonitrile;
at 50 ℃;
for 1h;
|
90% |
|
Diethyl methylmalonate;
With
sodium hydride;
In
tetrahydrofuran;
With
dibromamine-B;
In
tetrahydrofuran; dichloromethane;
at 0 ℃;
for 1h;
|
88% |
|
With
bromine; iodine;
|
|
|
at 65 ℃;
durch Bromieren;
|
|
|
With
bromine; calcium carbonate;
In
chloroform;
|
|
|
With
bromine;
In
tetrachloromethane;
Irradiation;
|
|
|
With
N-Bromosuccinimide; sodium hydride;
Yield given. Multistep reaction;
1.) THF, from 0 to 25 deg C, 1 h, 2.) THF, -78 deg C;
|
-
-
29263-94-3
diethyl bromomethylmalonate
| Conditions | Yield |
|---|---|
|
|
29263-94-3 Upstream products
-
609-08-5
Diethyl methylmalonate
29263-94-3 Downstream products
-
609-08-5
Diethyl methylmalonate
-
188407-70-7
diethyl 2-methyl-2-(2'-nitrophenoxy)malonate
-
71504-41-1
3t-(4-chloro-phenyl)-2,4-dimethyl-5-oxo-isoxazolidine-4r-carboxylic acid ethyl ester
-
92021-49-3
rac.-Benzyloxy-methylmalonsaeure-monoethylester-chlorid
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-
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-
3-BromophenylacetonitrileCAS：31938-07-5