606-45-1
- Product Name:Methyl 2-methoxybenzoate
- Molecular Formula:C9H10O3
- Purity:98% GC
- Molecular Weight:166.177
Product Details
Reputable factory supply Methyl 2-methoxybenzoate 606-45-1 in stock with high standard
- Molecular Formula:C9H10O3
- Molecular Weight:166.177
- Appearance/Colour:clear colorless to slightly yellow liquid
- Vapor Pressure:0.000722mmHg at 25°C
- Refractive Index:n20/D 1.534(lit.)
- Boiling Point:248°C(lit.)
- Flash Point:>230°F
- PSA:35.53000
- Density:1.157g/mLat 25°C(lit.)
- LogP:1.48180
Methyl 2-methoxybenzoate(Cas 606-45-1) Usage
|
Preparation |
By esterification of anisic acid with methanol, or from sodium anisate and dimethylsulfate in the presence of methanol |
|
Aroma threshold values |
Aroma characteristics at 1.0%: fruity, winey, fermented with a slightly musty and anisic nuance. |
|
Taste threshold values |
Taste characteristics at 10 ppm: fruity, anisic, fermented and winey with a good mouthfeel |
|
General Description |
FeCl2 catalyzed cross-coupling reaction between methyl 2-methoxybenzoate and diphenylmethane under various reaction conditions has been investigated. |
InChI:InChI=1/C9H12O3/c1-9(12-2)6-4-3-5-7(9)8(10)11/h3-7H,1-2H3,(H,10,11)/p-1
606-45-1 Relevant articles
Microwave-assisted synthes is of novel chiral receptors derived from deoxycholic acid and their molecular recognition properties
Ye, Ying,Suo, Yourui,Yang, Fang,Han, Lijuan
, p. 1812 - 1814 (2014)
Under microwave irradiation (MWI), novel...
Methylation with Dimethyl Carbonate/Dimethyl Sulfide Mixtures: An Integrated Process without Addition of Acid/Base and Formation of Residual Salts
Chan, Bun,Lui, Matthew Y.,Lui, Yuen Wai
, (2022/01/08)
Dimethyl sulfide, a major byproduct of t...
Antibacterial and Antiviral Activities of 1,3,4-Oxadiazole Thioether 4H-Chromen-4-one Derivatives
Cao, Xiao,Liu, Fang,Liu, Liwei,Liu, Tingting,Peng, Feng,Wang, Qifan,Xie, Chengwei,Xue, Wei,Yang, Jinsong
, p. 11085 - 11094 (2021/10/01)
Various 1,3,4-oxadiazole thioether 4H-ch...
GPR52 Antagonist Reduces Huntingtin Levels and Ameliorates Huntington's Disease-Related Phenotypes
Wang, Congcong,Zhang, Yu-Fang,Guo, Shimeng,Zhao, Quan,Zeng, Yanping,Xie, Zhicheng,Xie, Xin,Lu, Boxun,Hu, Youhong
, p. 941 - 957 (2020/11/30)
GPR52 is an orphan G protein-coupled rec...
Development of phenyltriazole thiol-based derivatives as highly potent inhibitors of DCN1-UBC12 interaction
Zhou, Wenjuan,Xu, Chenhao,Dong, Guanjun,Qiao, Hui,Yang, Jing,Liu, Hongmin,Ding, Lina,Sun, Kai,Zhao, Wen
, (2021/03/24)
Defective in cullin neddylation 1(DCN1) ...
606-45-1 Process route
-
-
99-50-3
3,4-Dihydroxybenzoic acid
-
-
89-86-1
4-hydroxysalicylic acid
-
-
149-91-7
3,4,5-trihydroxybenzoic acid
-
-
99-10-5
3,5-Dihydroxybenzoic acid
-
-
303-38-8
2,3-Dihydroxybenzoic acid
-
-
490-79-9
2,5-dihydroxybenzoic acid.
-
-
99-06-9
3-Carboxyphenol
-
-
69-72-7,25496-36-0,8052-31-1
salicylic acid
-
-
74-88-4
methyl iodide
-
-
99-96-7
4-hydroxy-benzoic acid
-
-
2150-41-6
methyl 2, 4-dimethoxybenzoate
-
-
606-45-1
2-methoxybenzoic acid methyl ester
-
-
5368-81-0
methyl 3-methoxybenzoate
-
-
121-98-2
methyl 4-methoxybenzoate
-
-
2150-38-1
methyl 3,4-dimethoxybenzoate
-
-
1916-07-0
3,4,5-trimethoxybenzoic acid methyl ester
-
-
2150-42-7
methyl 2,3-dimethoxybenzoate
-
-
2150-40-5
methyl 2,5-dimethoxybenzoate
-
-
2150-37-0
methyl 3,5-dimethoxybenzoate
| Conditions | Yield |
|---|---|
|
3,4-Dihydroxybenzoic acid; 4-hydroxysalicylic acid; 3,4,5-trihydroxybenzoic acid; 3,5-Dihydroxybenzoic acid; 2,3-Dihydroxybenzoic acid; 2,5-dihydroxybenzoic acid.; 3-Carboxyphenol; salicylic acid; 4-hydroxy-benzoic acid;
With
sodium hydride;
In
hexane; N,N-dimethyl-formamide;
at 25 ℃;
for 2h;
Inert atmosphere;
Cooling with ice;
methyl iodide;
In
hexane; N,N-dimethyl-formamide;
for 72h;
Inert atmosphere;
|
-
-
25414-22-6
2-methoxyfuran
-
-
292638-85-8,9003-21-8,96-33-3
acrylic acid methyl ester
-
-
606-45-1
2-methoxybenzoic acid methyl ester
-
-
5368-81-0
methyl 3-methoxybenzoate
| Conditions | Yield |
|---|---|
|
With
titanium; silicon;
for 0.416667h;
Microwave irradiation;
|
62 % Spectr. 10 % Spectr. |
606-45-1 Upstream products
-
67-56-1
methanol
-
610-97-9
o-iodo-methyl-benzoic acid
-
512-42-5
sodium methyl sulfate
-
7631-93-8
sodium o-methoxycarbonylphenolate
606-45-1 Downstream products
-
53847-40-8
γ-oxy-γ-(2-methoxy-phenyl)-pentane
-
10278-02-1
2-(2-methoxyphenyl)propene
-
54177-02-5
methyl 2-methoxybenzoylacetate
-
35244-11-2
2'-hydroxyflavone
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